Volume 585
Main Index

Issue 1, Pages 1-197 (1 August 1999)

New rhodium complexes with P,N-ligands possessing a hydroxy or methoxy group. Synthesis, characterization and application to hydroformylation of styrene Pages 1-6 Ioannis D. Kostas, Constantinos G. Screttas

π-Bonding in B–O ring species: Lewis acidity of Me3B3O3, synthesis of amine Me3B3O3 adducts, and the crystal and molecular structure of Me3B3O3.NH2iBu·MeB(OH)2 Pages 7-11 Michael A. Beckett, David S. Brassington, Paul Owen, Michael B. Hursthouse, Mark E. Light, K. M. Abdul Malik, K. Sukumar Varma

Bis(dicyclohexylammonium) (oxalato)(pyridine-2,6-dicarboxylato)dibutylstannate 3.5 hydrate, the first crystallographic example of a mixed-chelate diorganotin(IV) compound Pages 12-17 Seik Weng Ng

Si2Me4-bridged zirconocene dichlorides: crystal and molecular structure of meso-Si2Me4(3-SiMe3–C9H5)2ZrCl2 Pages 18-25 Odilia Pérez-Camacho, Sergei Ya. Knjazhanski, Gregorio Cadenas, María J. Rosales-Hoz, Marco A. Leyva

Synthesis of several functionalized cis-diisocyanide and fac-triisocyanide metal complexes Pages 26-34 Luqin Yang, Kung-Kuai Cheung, Andreas Mayr

Evidence of single electron transfer in the diastereoselective synthesis of β-stannylketones Pages 35-42 A. B. Chopa, A. P. Murray, M. T. Lockhart

Stereoselective reactivity of diastereotopic carbon–carbon triple bonds induced by chiral orthosubstituted arene tricarbonyl chromium complexes. Diastereoselective Co2(CO)8 complexation and LiAlH4 reduction Pages 43-52 Bertrand Caro, Marie-Claude Sénéchal-Tocquer, Françoise Robin-Le Guen, Pascal LePoul

The first alkyne-dicobaltcarbonyl complex with a bidentate chiral ligand with Co–P and Co–N coordination Pages 53-58 Jaume Castro, Albert Moyano, Miquel A. Pericàs, Antoni Riera, Angel Alvarez-Larena, Joan F. Piniella

Synthesis and crystal structure of bis(2-dimethylaminoethylindenyl) divalent organolanthanides (Ln=Sm, Yb) Pages 59-62 Changtao Qian, Hengfeng Li, Jie Sun, Wanli Nie

Facile synthesis of σ,μ-iminoacyl bridged butterfly clusters (μ-RE)(σ,μ-ArC=NAr′)Fe2(CO)6 (E=S, Se) Pages 63-67 Chao-Guo Yan, Jing Sun, Jie Sun

Investigation of the reactivity of the phosphorus---hydrogen bond in Cp′RuL1L2Cl complexes with diphenylphosphine ligands Pages 68-82 Román Torres-Lubián, M. Jesús Rosales-Hoz, Atta M. Arif, Richard D. Ernst, M. Angeles Paz-Sandoval

Preparation of new acetylide and vinylidene complexes of ruthenium Pages 83-92 Gabriele Albertin, Stefano Antoniutti, Emilio Bordignon, Manuel Granzotto

C–H activation of a MeN grouping in one of the CH2NMe2 ortho substituents of a NCN ‘pincer’ ligand in tungsten chemistry: X-ray structure of [WCl2(NPh)(C6H3{CH2NMeCH2}-2-{CH2NMe2}-6)] Pages 93-99 Jim A. M. Brandts, Elbertus Kruiswijk, Jaap Boersma, Anthony L. Spek, Gerard van Koten

Triruthenium clusters derived from the reactions of [Ru3(CO)12] with benzothiazole, pyrimidine-2-thione and benzimidazole-2-thione; X-ray structures of [Ru3(μ-H)(μ-2,3-η2-NSC7H4)(CO)10] and [Ru3(μ-H)(μ3-η2-SN2C4H3)(CO)9] Pages 100-105 Rahima Dilshad, Khandakar M. Hanif, Michael B. Hursthouse, Shariff E. Kabir, K. M. Abdul Malik, Edward Rosenberg

The structure of bicyclic ferrocenylmethylene substituted 2-pyrazolines and their reactions with azodicarboxylic acid N-phenylimide Pages 106-114 Elena I. Klimova, Marcos Martínez García, Tatiana Klimova Berestneva, Cecilio Alvarez Toledano, Ruben Alfredo Toskano, Lena Ruíz Ramírez

The chemistry of metallacyclic alkenylcarbene complexes: Part 9. Synthesis and reactions of chelated η2-alkene- and η3-allyl-carbene complexes of cobalt, manganese and chromium Pages 115-126 Sven-Eric Eigemann, Rainer Schobert

Syntheses and solid-state structures of mono- and dialkyl(methylsulfonato)boranes Pages 127-133 Rainer Papp, Fernando B. SomozaJr., Joachim Sieler, Steffen Blaurock, Evamarie Hey-Hawkins

Reductive coupling of alkynes by oxobis(diethyldithiocarbamato)molybdenum(IV)–sodium borohydride Pages 134-140 C. Conn, D. Lloyd-Jones, G. S. K. Kannangara, A. T. Baker

Reactions of thioarsines with metal carbonyls: synthesis and structural characterisation of [Fe2(CO)6(μ-AsMe2)(μ-SPh)], [Fe2Cp2(CO)2(μ-AsPh2)(μ-SPh)], [Mn2(CO)8(μ-AsPh2)(μ-SPh)] and [Co3(μ3-S)(μ-AsPh2)(CO)6AsPh3] Pages 141-149 Gráinne Conole, John E. Davies, Jason D. King, Martin J. Mays, Mary McPartlin, Harold R. Powell, Paul R. Raithby

Electronegativity equilibration and organometallic thermochemistry: the strengths of carbon–carbon bonds in metal alkyls Pages 150-153 Derek W. Smith

Sandwich and half-sandwich niobium imido complexes: X-ray crystal structure of [Nb(=NAr)Cp′2Cl] (Cp′=η5-C5H4SiMe3, Ar=C6H4OMe-4) Pages 154-161 Antonio Antiñolo, Mariano Fajardo, Carmen Huertas, Antonio Otero, Sanjiv Prashar, Ana M. Rodriguez

An organometallic sol–gel route to layered zinc phenylphosphonate and encapsulation studies with η6-(C6H6)Cr(CO)3 Pages 162-166 Robert W. Deemie, Muralidhar Rao, D. Andrew Knight

2,6-Dimethoxyphenylphosphetane sulfide—synthesis, structure and exploratory photochemistry Pages 167-173 Hu Qian, Peter P. Gaspar, Nigam P. Rath

First Sonogashira coupling reactions with the chlorobenzeneCr(CO)2PPh3 complex Pages 174-178 Markus Ansorge, Thomas J. J. Müller

Structure and reactivity of four-membered titanacycles—theoretical studies Pages 179-188 Uwe Böhme, Rüdiger Beckhaus

Head-to-head versus head-to-tail dimerizations of transient silenes—the synthesis and reactivity of 2-(8-dimethylamino-1-naphthyl)- and 2-(4-dimethylamino-1-naphthyl)-1,1-bis(trimethylsilyl)silene Pages 189-197 Douglas Hoffmann, Helmut Reinke, Hartmut Oehme

Issue 2, Pages 201-362 (15 August 1999)

Crown compounds for anions. Spectroscopic and theoretical studies of complexation of borohydride anions with cyclic trimeric perfluoro-o-phenylenemercury Pages 201-210 L. N. Saitkulova, E. V. Bakhmutova, E. S. Shubina, I. A. Tikhonova, G. G. Furin, V. I. Bakhmutov, N. P. Gambaryan, A. L. Chistyakov, I. V. Stankevich, V. B. Shur, L. M. Epstein

Novel Si–Sn ring systems with distanna and tristanna moieties Pages 211-214 U. Hermann, M. Schürmann, F. Uhlig

Seven-coordinate complexes of molybdenum(II) containing a trichlorogermyl ligand: X-ray crystal structure of a novel [Mo(GeCl3)2(CO)2(NCEt)3] Pages 215-224 Teresa Szymaska-Buzar, Tadeusz Gowiak, Izabela Czeluniak

Koordinationschemie funktioneller Phosphane VIII. Tetracarbonylkomplexe des Wolframs und Molybdäns mit 2-(Diphenylphosphanyl)anilin-Liganden Pages 225-233 Lutz Dahlenburg, Konrad Herbst, Heinz Berke

Mononuclear half-sandwich rhodium complexes containing phenylchalcogenolato ligands: a multinuclear (1H, 13C, 31P, 77Se, 103Rh, 125Te) magnetic resonance study Pages 234-240 Max Herberhold, Thomas Daniel, Daniela Daschner, Wolfgang Milius, Bernd Wrackmeyer

Palladium complexes with bridged and unbridged benzimidazolin-2-ylidene ligands Pages 241-245 F. Ekkehardt Hahn, Margarete Foth

Syntheses and characterization of a series of carbonylruthenium(I) and (II) complexes containing pyridyl ligands Pages 246-252 Li Xu, Yoichi Sasaki

La reaction de Diels–Alder catalysee par les sels de bismuth (III) Pages 253-255 Bernard Garrigues, Adyl Oussaid

Unexpected regioselective formation of internal η3-allylpalladium chloride complexes from terminal alkenes and palladium chloride in 1,2-dichloroethane Pages 256-258 Abdelkhalek Riahi, Jacques Muzart

Modes of complexation of bis-aminals of linear tetraamines with Group 6 metal carbonyls Pages 259-265 Gwénaëlle Hervé, Nathalie Le Bris, Hélène Bernard, Jean-Jacques Yaouanc, Hervé des Abbayes, Henri Handel

Reactivity studies of trimethylaluminum, trimethylgallium, and trimethylindium with a series of five silylamines: molecular structure of trans-[Me2InN(Me)SiMe3]2 Pages 266-274 Eric K. Styron, Steven J. Schauer, Charles H. Lake, Charles L. Watkins, Larry K. Krannich

Synthesis and characterization of zirconium pentafluorophenyl complexes: X-ray crystal structures of [ZrCl2(C6F5)42−] and [ZrF2(C6F5)53−] Pages 275-284 Melissa J. Nelsen, Gregory S. Girolami

The crystal structure of a trinuclear anion, [(t-Bu2Sb)2Sb]− formed by reaction of cyclo-(t-Bu4Sb4) with potassium, and the four-membered rings, cyclo-(t-Bu4EnSb4−n) (E=P, n=0–3; E=As, n=0–2) Pages 285-289 H. Althaus, H. J. Breunig, J. Probst, R. Rösler, E. Lork

Complexes of Rh(I) with phosphite derivatives of codeine Pages 290-293 K. N. Gavrilov, A. V. Korostylev, O. G. Bondarev, A. I. Polosukhin, V. A. Davankov

Isocyanide–Group 5 complexes and metal-centred C–C coupling Pages 294-307 Dieter Rehder, Christian Böttcher, César Collazo, Ronald Hedelt, Hauke Schmidt

Alkylation of cyclopentadienyl rings in the reactions of nickelocene with organolithium compounds Pages 308-314 S. Pasynkiewicz, A. Pietrzykowski, L. Bukowska, L. Jerzykiewicz

Chirale Bisphosphane IX. Kationische Rhodium(I)-Komplexe mit (1S,2S)-Cyclopentan-1,2-diyl-bis(dialkylphosphan)-Liganden, [(1S,2S)-C5H8(PR2)2Rh(1,5-COD)]O3SCF3: Synthesen, Strukturen und katalytische Anwendungen, Pages 315-325 Lutz Dahlenburg, Volker Kurth

On the structure and reaction with pyridine of o-methoxyphenyllead acetates Pages 326-330 Jonathan E. H. Buston, Richard G. Compton, Michael A. Leech, Mark G. Moloney

Keto-acid chloride and diketone intermediates in the acylation of ferrocene by arylene bis-acid chlorides. Crystal and molecular structure of 4-ferrocenylcarbonyl-4′-chlorocarbonylbiphenyl: intermolecular association by means of strong C–HO hydrogen bonds and ππ stacking interactions Pages 331-340 S. Zaka Ahmed, George Ferguson, Christopher Glidewell

Kondensationen von Silylhydrazinen und Estern zu Silylhydrazonen und Pyrazolnen Pages 341-347 Henning Witte-Abel, Christian Drost, Uwe Klingebiel, Mathias Noltemeyer

Combining N-heterocyclic carbenes and phosphines: improved palladium(II) catalysts for aryl coupling reactions Pages 348-352 Thomas Weskamp, Volker P. W. Böhm, Wolfgang A. Herrmann

Index Pages 355-356

Index Pages 357-362